Chemical Engineering Thermodynamics - II

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CHEMICAL ENGINEERING THERMODYNAMICS BE04005041
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Code: BE04005041 Credits: 3 Semester 4 Chemical

Chemical Engineering Thermodynamics - II

Get the full GTU study material, English & Gujarati textbook PDFs, syllabus curriculum, and solved previous year question papers.

Chemical Engineering Thermodynamics - II Syllabus — Unit-wise Content

The official GTU curriculum for Chemical Engineering Thermodynamics - II (subject code BE04005041) as prescribed for Chemical · Semester 4 divides the course into 3 units, covering 50 listed topics. The unit-wise breakdown below is read from the GTU syllabus document for this subject code, so you can check what the course actually covers before deciding which papers to attempt.

Download the official syllabus PDF (BE04005041)

Unit 1 PHASE EQUILIBRIA

15 lecture hours

  • VAPOUR/LIQUID EQUILIBRIUM(VLE) Introduction
  • The Nature of Equilibrium
  • The Phase Rule
  • Duhem’s Theorem
  • VLE- Qualitative Behaviour
  • Azeotropic Mixtures
  • Retrograde condensation
  • Simple Models for Vapour/Liquid Equilibrium
  • Raoult’s Law, Dew point and Bubble point Calculations with Raoult’s Law, Henry’s law, VLE by Modified Raoult’s Law, VLE from K-Value Correlations
  • Flash Calculations
  • The Gamma / Phi Formulation of VLE, An introduction to Equilibrium and stability
  • liquid-liquid equilibrium (LLE)
  • solid-liquid equilibrium
  • Vapor-Liquid-liquid equilibrium (VLLE)
  • Solid- Liquid equilibrium (SLE)
  • Solid-Vapor equilibrium (SVE) etc

Unit 2 SOLUTION THERMODYNAMICS

18 lecture hours

  • THEORY Fundamental Property Relation
  • The Chemical Potential as a Criterion for Phase Equilibria
  • Partial Properties
  • Equations Relating Molar and Partial Molar Properties
  • The Partial Molar Gibbs Energy and the Generalized Gibbs-Duhem Equation
  • Partial Properties in Binary Solutions
  • Relations among Partial Properties
  • The Ideal Gas Mixture model
  • The Partial Molar Gibbs Energy and Fugacity
  • Fugacity and Fugacity Coefficient: Pure Species and for Species in Solution
  • The Ideal Solution Model
  • The Lewis/Randall Rule
  • Excess Properties
  • The Excess Gibbs energy and activity coefficient
  • nature of excess property APPLICATIONS Liquid-Phase Properties from VLE Data
  • Composition Dependence of Liquid- Phase Fugacities for Species in a Binary Solution
  • Excess Gibbs Energy
  • Data Reduction
  • Thermodynamic Consistency by Integral or Area Test Method
  • Models for the Excess Gibbs Energy
  • Margules Equations
  • Van-Laar Equations
  • Local Composition Models such as NRTL Equation
  • UNIQUAC Equation
  • UNIFAC Method Program Name: Bachelor of Engineering Level: UG Branch: Chemical Engineering Subject Code: BE04005041 Subject Name: Chemical Engineering Thermodynamics-2

Unit 3 CHEMICAL REACTION EQUILIBRIA

12 lecture hours

  • The reaction coordinates
  • Application of equilibrium criteria to chemical reactions
  • The standard Gibbs free energy change and the equilibrium constant
  • Effect temperature on equilibrium constant
  • Evaluation of the equilibrium constant
  • Relation of equilibrium constant to composition for gas phase and liquid phase reactions
  • calculation of equilibrium conversion for single reaction
  • The phase rule and Duhem’s theorem for reacting systems
  • introduction to multi-reaction equilibria

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